Volume 553
Main Index

Issues 1-2, Pages 1-524 (25 February 1998)

Thermal reactions of alkyl(hydrido)(hydrosilyl)iridium(III) complexes: generation of a hydrido(silylene)iridium(I) species via the reductive elimination of alkane and 1,2-H-shift from the silicon atom to the Ir(I) metal center Pages 1-13 Masaaki Okazaki, Hiromi Tobita, Yasuro Kawano, Shinji Inomata, Hiroshi Ogino

Synthesis and crystal structure of a zirconium(III) diacetylide tweezer complex: [(η5-C5HMe4)2Zr(η1-CCSiMe3)2]-K+ Pages 15-22 Vojtech Varga, Jörg Hiller, Ulf Thewalt, Miroslav Poláek, Karel Mach

Formation and X-ray structure of [{O(Ph2SiONa)2}4·(NaOH)·(H2O)·(7 pyridine)]·(toluene)·(pyridine) incorporating a unique assembly of three fused Na4O4 cubane units and a μ3-water molecule Pages 23-29 Isaac Abrahams, Michael Lazell, Majid Motevalli, Syed. A. A. Shah, Alice C. Sullivan

Synthese und Reaktionsverhalten monomerer Bis(η2-Alkin)-Kupfer(I)-Fluorid- und-Kupfer(I)-Hydrid-Komplexe Pages 31-38 Katrin Köhler, Hans Pritzkow, Heinrich Lang

Wasserlösliche Phosphane VII: Synthese, Koordinationschemie und Templatreaktionen PH-funktioneller Bis(phosphinoethyl)amine Pages 39-52 Antonella Heßler, Stefan Kucken, Othmar Stelzer, William S. Sheldrick

Synthesis of bipyridine and biquinoline complexes of group 4 metallocenes Pages 53-57 Leslie A. Bishop, Marie A. Turner, Lawrence B. Kool

Vibrational spectra and structure of dicyclopentadienylzinc Pages 59-65 O. G. Garkusha, B. V. Lokshin, G. K. Borisov

Lewis acid catalysed M-ene, H-ene, and cycloaddition reactions of allylic stannanes and silanes with methyl propiolate Pages 67-72 Hai-Shan Dang, Alwyn G. Davies

Tetraferrocenyl-[3]-cumulene  Pages 73-81 Benno Bildstein, Manuela Schweiger, Holger Kopacka, Klaus Wurst

Thioethercarboxylates in palladium chemistry: First proof of hemilabile properties of S–O ligands Pages 83-90 Wolfgang H. Meyer, Robert Brüll, Helgard G. Raubenheimer, Catharine Thompson, Gert J. Kruger

The CoCl2/Ph(Et)2N:BH3/CO system: Reactions of the borane and cobalt carbonyl species Pages 91-97 M. Lakshmi Narayana Rao, Mariappan Periasamy

Studies on the formation of uniform η3-coordinated triphos-Mo(0)-complexes Pages 99-102 Achim Kless, Jens Holz, Helmut Reinke, Armin Börner

Conversion of η2-phosphinocarbene complexes into tungstaphosphabicyclo[1.1.0]butanone units Pages 103-109 Th. Lehotkay, K. Wurst, P. Jaitner, F. R. Kreißl

X-ray analysis and NMR-studies of E- and Z-1,2-bis(fluorodimethylsilyl)-1,2-diphenylethenes Pages 111-114 V. Plack, P. Sakhaii, A. Fischer, P. G. Jones, R. Schmutzler, K. Tamao, G. -R. Sun

Organometallic nickel(II) complexes with substituted benzonitrile ligands. Synthesis, electrochemical studies and non-linear optical properties. The X-ray crystal structure of [Ni(η5-C5H5){P(C6H5)3}(NCC6H4NH2)][PF6] Pages 115-128 Alberto R. Dias, M. Helena Garcia, Paulo Mendes, M. Fátima M. Piedade, M. Teresa Duarte, Maria J. Calhorda, Carlo Mealli, W. Wenseleers, A. W. Gerbrandij, Etienne Goovaerts

Universal method for trimethylsilylation of acetylenic alcohols and glycols Pages 129-133 Maria Demina, Andrey Velikanov, Alevtina Medvedeva, Lyudmila Larina, Mikhail Voronkov

A convenient synthesis of a sterically protected 1,4-diphosphabutatriene and its pentacarbonyltungsten complexes Pages 135-140 Shigekazu Ito, Kozo Toyota, Masaaki Yoshifuji

Synthesis and structure of alkali metal ‘ate' complexes in the yttrium/2,6-dimethylphenoxide system Pages 141-148 William J. Evans, Mohammad A. Ansari, Joseph W. Ziller, Saeed I. Khan

Synthesis and characterization of a series of sila-bridged diiron complexes (E)[(η5-t-BuC5H3)Fe(CO)]2(μ-CO)2 (E=Me2Si, Me2SiSiMe2, Me2SiOSiMe2). The molecular structures of cis- and trans-(Me2Si)[η5-t-BuC5H3)Fe(CO)]2(μ-CO)2 Pages 149-155 Yongqiang Zhang, Shansheng Xu, Gonglu Tian, Xiuzhong Zhou, Jie Sun

Ruthenium-mediated selective head-to-tail dimerization of acrylic and α,β-unsaturated carbonyl compounds: generation of an acrylate-hydride complex C5Me5Ru(PCy3)(CH2=CHCO2Et)H Pages 157-161 Chae S. Yi, Nianhong Liu

Photochemical reactions of digermanyl-substituted naphthalenes: The germyl migration to the aromatic ring Pages 163-171 Kunio Mochida, Hiroyuki Ginyama, Masae Takahashi, Mitsuo Kira

para-Fluoro benzyl substituted bis(indenyl) metallocenes as catalyst precursors in ethene polymerization Pages 173-178 Gerhard Jany, Marina Gustafsson, Timo Repo, Erkki Aitola, José A. Dobado, Martti Klinga, Markku Leskelä

Synthesis of the first mono(cyclopentadienyl)lanthanide Schiff base complex bearing C2-symmetric tetradentate ligand: crystal structure of [(η5-C5H5)Yb(μ-OC20H20N2O)]2(μ-THF)(THF) Pages 179-181 Qiancai Liu, Mengxian Ding

Synthesis of β-keto Fischer carbene complexes Pages 183-191 Craig A. Merlic, Feng Wu

Reactions of fullerenols C60(OH)x (x=12, 18) with trialkoxysilanes (RO)3Si(CH2)3X (R=Me, X=Cl; R=Et, X=NH2) Pages 193-197 Marta Iglesias, Amelia Santos

Asymmetric transfer hydrogenation of acrylic acids catalyzed by rhodium(I) complexes of diphosphine ligands Pages 199-204 A. M. d'A. Rocha Gonsalves, J. C. Bayón, M. M. Pereira, M. E. S. Serra, J. P. R. Pereira

Selbstimmobilisierende Metallocenkatalysatoren Pages 205-220 Bernd Peifer, Wolfgang Milius, Helmut G. Alt

Study of cyclic borinates obtained from piperidine- and piperazine alcohols by spectroscopic methods and X-ray crystallography Pages 221-239 Herbert Höpfl, Norberto Farfán, Dolores Castillo, Rosa Santillan, Atilano Gutierrez, Jean-Claude Daran

Neue Wolfram(VI) carbin- und Carbenkomplexe durch Reaktion von Chlorocarbinkomplexen mit Nukleophilen. Neue Katalysatoren für die ringöffnende metathetische Polymerisation von Cycloolefinen Pages 241-251 Wolfgang Kläui, Thomas Hardt

Electrochemical reduction of some [(η5-Cyclopentadienyl) (η6-arene) iron(II)][PF6] complexes bearing an imine or a nitrone function in benzylic position of the arene ligand Pages 253-267 Fabrice Pierre, Andrea Stricker, Claude Moinet, Sourisak Sinbandhit, Loïc Toupet

A thermodynamic study of the electron transfer chain catalyzed substitution of triphenylphosphine for iodide on CpFe(CO)2I Pages 269-275 Zenghe Liu, Stephen L. Gipson

Synthesis and characterization of Ti(C5H5)(2,4-C7H11) and Ti(2,4-C7H11)2[, chiral phosphite adducts of an open and a half open titanocene Pages 277-284 Derk Vos, Atta M. Arif, Richard D. Ernst

Enantioselective catalysis: Part 114. Chirostructural analysis of bis(diphenylphosphanyl)ethane transition metal chelates Pages 285-306 Henri Brunner, Andreas Winter, Josef Breu

Fixation of triruthenium clusters on melamine: synthesis and structure of [Ru3(μ2-H)(CO)9{μ3,η2-NHC3N3(NH2)2}], cis-[{Ru3(μ2-H)(CO)9}2{μ3,η2:μ3,η2-NHC3N3(NH2)}] and trans-[{Ru3(μ2-H)(CO)9}2{μ3,η2:μ3,η2-NHC3N3(NH2)}] Pages 307-315 Reto Dorta, Helen Stoeckli-Evans, Ulf Bodensieck, Georg Süss-Fink

Silyl-Komplexe des Molybdäns und Wolframs. Synthese, Reaktivität und Struktur Pages 317-329 Stefan H. A. Petri, Beate Neumann, Hans-Georg Stammler, Peter Jutzi

ansa-Metallocene derivatives: XLI. Chiral ansa-Magnesocene complexes–syntheses, crystal structures and structural dynamics in solution Pages 331-343 Hans-Robert H. Damrau, Armin Geyer, Marc-Heinrich Prosenc, Armin Weeber, Frank Schaper, Hans-Herbert Brintzinger

Tin(IV) and organotin(IV) complexes containing mono or bidentate N-donor ligands: III. 1-methylimidazole derivatives: synthesis, spectroscopic and structural characterization Pages 345-369 C. Pettinari, M. Pellei, M. Miliani, A. Cingolani, A. Cassetta, L. Barba, A. Pifferi, E. Rivarola

Synthesis of triruthenium clusters containing mixed bridging phosphido ligands: X-ray crystal structures of [Ru3(CO)7(μ-H)(μ-PBu2t)(μ-PCy2)2] and the electron-deficient complex [Ru3(μ-CO)(CO)5(μ-H)2(μ-PBu2t)2(Bu2tPH)] Pages 371-378 Marion Graf, Kurt Merzweiler, Clemens Bruhn, Hans-Christian Böttcher

Synthesies, properties and crystal structures of ionic [Al2(μ,η2-thffo)2(EtOH)4Cl2]Cl2, [Al3(μ,η2-thffo)4Cl4][AlEtCl3] and tetranuclear [Al4(μ,η2-thffo)4(μ-OEt)2Cl6] (thffo=OCH2CH(CH2)3O) compounds Pages 379-385 Piotr Sobota, Józef Utko, Anatoly I. Brusilovets, Lucjan B. Jerzykiewicz

Synthesis and structure of sulfonamido cyclopentadiene titanium complexes: X-ray structure of Ti(η5:σ-C5H4CH2CH2NSO2C6H4CH3)Cl2 Pages 387-392 Cornelis Lensink

Cyclooctatetraenyl complexes of the early transition metals and lanthanides: X. The first organometallic triple decker sandwich complexes of the lanthanides Pages 393-395 Peter Poremba, Frank T. Edelmann

Utility of hydridotributyltin as both reductant and hydride transfer reagent in organotransition metal chemistry: I. A convenient synthesis of the organoditantalum(IV) hydrides (η-C5Me4R)2Ta2(μ-H)2Cl4 (R=Me, Et) from (η-C5Me4R)TaCl4, and probes of the possible reaction pathways Pages 397-403 Ting-Yu Lee, Louis Messerle

C(3) aurated 1,4-benzodiazepin-2-ones. Synthesis and characterization. Crystal structure of (L)Au[P(C6H4CH3-4)3] (HL=7-chloro-1,3-dihydro-1-methyl-5-phenyl-2H-1,4-benzodiazepin-2-one, DIAZEPAM) Pages 405-415 Giovanni Minghetti, Antonio Zucca, Maria Agostina Cinellu, Sergio Stoccoro, Mario Manassero, Mirella Sansoni

Synthesis of ruthenium vinylidene complexes with dppe ligand and their cyclopropenation reaction Pages 417-425 Chao-Wan Chang, Pei-Chen Ting, Ying-Chih Lin, Gene-Hsiang Lee, Yu Wang

Intermolecular coupling reactions of inversely polarized carbene ligands starting from the Cp2*Ti=C=CH2 intermediate and chromium carbene complexes Pages 427-432 Rüdiger Beckhaus, Jürgen Oster

Funktionalisierte cyclopentadienylliganden für den aufbau von tripod-komplexen: synthese und komplexchemie Pages 433-441 Björn Antelmann, Gottfried Huttner, Ute Winterhalter

Mehrfachbindungen zwischen Hauptgruppenelementen und Übergangsmetallen: CLXVI. Molekulare Organorhenium-Vorstufen für CVD-prozesse Pages 443-452 Wolfgang A. Herrmann, Wolfgang M. Wachter, Fritz E. Kühn, Richard W. Fischer

Heteroligand substitution in clusters of ruthenium and cobalt Pages 453-461 Tiina M. Räsänen, Sirpa Jääskeläinen, Tapani A. Pakkanen

Synthesis and reactivity of a range of 2-ferrocenyl-3-pivaloyl-1,3-oxazolidin-5-ones Pages 463-468 Francisco Alonso, Stephen G. Davies, Christian A. P. Smethurst

Isomerization of olefins in a two-phase system by homogeneous water-soluble nickel complexes Pages 469-471 Hervé Bricout, André Mortreux, Eric Monflier

Modelling intermediates in the catalytic carbonylation of CH2I2 to malonate esters; Evidence for a ketene pathway Pages 473-476 William S. Weston, Philip Lightfoot, David J. Cole-Hamilton

A facile access to CpCr (acac)Cl and related systems Pages 477-479 Oliver Heinemann, Peter W. Jolly, Carl Krüger, Glenn P. J. Verhovnik

An unusual rearrangement of 1-trimethylsiloxy-3-bromomagnesium-2-propyne Pages 481-482 A. S. Medvedeva, V. V. Novokshonov, M. M. Demina, M. G. Voronkov

η4-quinone, η5-semiquinone and η6-hydroquinone complexes of pentamethylcyclopentadienyl iridium. X-ray molecular structure of [Cp*Ir(η4-1,4 benzoquinone)] Pages 483-485 Jean Le Bras, H. Amouri, Jacqueline Vaissermann

Synthesis and properties of dithienosiloles Pages 487-491 Joji Ohshita, Mitsunori Nodono, Tsuguo Watanabe, Yoshiatsu Ueno, Atsutaka Kunai, Yutaka Harima, Kazuo Yamashita, Mitsuo Ishikawa

Palladium-catalyzed metathesis of phenylalkyl- or chloroalkyldigermanes with allylic chlorides at room temperature Pages 493-496 Taichi Nakano, Tatsuki Enokido, Sigeyuki Noda, Nao-aki A-ihara, Masanori Kosugi, Toshihiko Migita

First examples of acylgold(I) complexes RCOAuPPh3 (R=Me, n-Bu, t-Bu, Ph) trapped as oxygen coordinated ligands L at one of rhenium atoms in Re2(μ-PPh2)2(CO)7(ax-L) Pages 497-501 Hans-Jürgen Haupt, Dina Petters, Ulrich Flörke

Synthesis, structural characterisation and dynamic behaviour of pentafulvalenyldilanthanide(II) complexes Pages 503-506 François Nief, Louis Ricard

Synthesis of racemic chiral-at-metal complexes of the group 4 metals by a lithium chloride catalysed ligand redistribution reaction Pages 507-509 Suzanne L. Hart, Andrew McCamley, Peter J. McCormack, Paul C. Taylor

Different reaction modes of supermesitylphosphaalkyne with [W(CO)5thf]-unusual C-H-activation forming an indanyl substituent Pages 511-516 Peter Kramkowski, Manfred Scheer, Gerhard Baum

Electronic spectrum and photoreactivity of dimethyl(1,5-cyclooctadiene)-platinum(II) Pages 517-519 Horst Kunkely, Arnd Vogler

Book Review Pages 521-524